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The accuracy of the Conductivity measurement depends on 4 elements:

• Measurement device
• Electrode
• Standard solutions
• Good Laboratory Measurement

These will be explained in the following paragraphs.

This error indicates the possible deviation of the actual conductivity of a non calibrated measurement when using an ideal electrode. The device error is the sum of 2 different errors: repetition error and linearity error.

The error of the device is given in the technical specifications. A Conductivity meter usually has several measurement ranges, therefore is the error usually given as a percentage of the full scale (% f.s.) of the range. This allows to calculate the exact absolute device error value for each range separately.

e.g.

Error specification: 0.5% f.s. of range

• Range up to 20.00 µS/cm: max. device error = 0.10 µS/cm
• Range up to 2000 µS/cm:max. device error = 10 µS/cm

This doesn't mean that when you measure a conductivity of 1000 µS/cm, a few moments later the device might indicate 10 µS more or less in the same solution. No, the device remains quite stable and has a very small repetition error.

The device error might be minimized after a proper calibration and measurements near the calibration points. The further the measurements deviate of the calibration points, the possible error will increase again towards the max. device error. This because of the possible linearity error.

A Conductivity electrode is a passive element which remains also rather stable. The error will mostly be coming from impurities or small construction differences. The measurement error is here also the sum of small repetition errors and larger linearity errors. The linearity error is increasing for most electrodes when measuring in higher ranges. Plastic body cells are mostly not suitable for higher conductivity measurements.

Elimination of the error is done by choosing a calibration point(s) near the measurements to be done.

The standards that are used for the calibration are the largest cause of error which cannot be eliminated. The solutions have mostly an accuracy of 1% or 0.5%. This needs to be checked with the supplier or manufacturer of the solutions.

• While calibrating or measuring all solutions should be stirred gently (e.g. with a magnetic stirrer) to ensure the electrode gives a true representation of the beaker contents.
• Always check there are no air bubbles trapped in the cell while measuring.
• Calibration solutions should be chosen which have values near the expected sample value (see previous elements).
• Only fresh calibration solutions should be used! Changing all solutions daily is a good practice.
• All solutions should be maintained at equal temperature.
• Rinse the electrode twice between measurements and calibrations: first thoroughly in distilled water and then with a small disposable amount of the next sample to be measured.
• Allow the electrodes sufficient time to stabilise while calibrating or measuring. A stability indicator on most of our meters prompts the user when readings should be taken.

These measurement practices allow to keep the errors low, error due to contaminations of the solutions, temperature differences or not taking enough time.