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commonaskedquestions_ise [22/02/2019 10:51]
pieter
commonaskedquestions_ise [22/02/2019 10:54]
pieter
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 =====Frequently Asked Questions (Ion-selective electrodes)===== =====Frequently Asked Questions (Ion-selective electrodes)=====
-===How often do you need to calibrate?=== +====How often do you need to calibrate?==== 
-Recalibrate at least once a week, or daily if in doubt of your results being accurate or reproducible. Check the manual for more information on each ISE about the expected stability. +Calibrate at least once a week, preferred is **daily**. Calibrate if in doubt of your results being accurate or reproducible. Check the manual for more information on each ISE about the expected stability. When subject to temperature changes, mind that a difference of 1°C causes a measurement error of 2%
-===How long after being opened or made are standards good?===+====How long after being opened or made are standards good?====
 The stock standard will last at least six months before discarding, whereas diluted standards treated with ISA/pH buffer should be prepared weekly. The stock standard will last at least six months before discarding, whereas diluted standards treated with ISA/pH buffer should be prepared weekly.
-===How do you store the electrodes?===+====How do you store the electrodes?====
 It is best to store them dry when they are not to be used in the next week or so. Empty out the filling solution in the gas-sensing electrode. For shorter periods, store in dilute standard approximating the sample concentration, and ISA/pH buffer added when required. It is best to store them dry when they are not to be used in the next week or so. Empty out the filling solution in the gas-sensing electrode. For shorter periods, store in dilute standard approximating the sample concentration, and ISA/pH buffer added when required.
-===Can you do temperature compensation with ISE?===+====Can you do temperature compensation with ISE?====
 Yes, it is possible, but somewhat difficult.  Yes, it is possible, but somewhat difficult. 
   - You have to know the isopotential point for a given electrode system.    - You have to know the isopotential point for a given electrode system. 
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   - Very little isopotential point data for ISE's is available at this time.   - Very little isopotential point data for ISE's is available at this time.
 **It is best to standardize and measure samples at the same temperature without using temperature compensation.** **It is best to standardize and measure samples at the same temperature without using temperature compensation.**
-===Can you do in-line continuous ISE measurement without treating the sample?===+====Can you do in-line continuous ISE measurement without treating the sample?====
 Yes, direct measurement is possible in many cases without ISA/buffer addition to the sample stream. However, Fluoride, Sulfide, Ammonia, and Sodium Electrodes do require pH adjustment and must have ISA/ buffer added to the sample stream. Yes, direct measurement is possible in many cases without ISA/buffer addition to the sample stream. However, Fluoride, Sulfide, Ammonia, and Sodium Electrodes do require pH adjustment and must have ISA/ buffer added to the sample stream.
-===Which standards should be used with the ISE?===+====Which standards should be used with the ISE?====
 The most obvious choice will be determined by what The most obvious choice will be determined by what
 concentration units are desired (e.g. ppm as what?). Also, if concentration units are desired (e.g. ppm as what?). Also, if
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 sulfate with a lead electrode), use a stock standard of the sulfate with a lead electrode), use a stock standard of the
 ion to be measured (e.g. sulfate). ion to be measured (e.g. sulfate).
-===Why buy a combination electrode instead of separate ones?===+====Why buy a combination electrode instead of separate ones?====
 Advantages:  Advantages: 
   * no external reference electrode needed    * no external reference electrode needed 
commonaskedquestions_ise.txt · Last modified: 22/02/2019 10:55 by pieter